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Toy Story 3

Play as Zurg (PS3 Exclusive)
Finish the first two missions. Zurg will be available in Al's Toy Barn to purchase. When you do, a Zurg pod will be in Slinky's Corral. Enter it.

Weapons
UFO Gun - Unlock in Story Mode / Available after the "Blow up the Dam" / $2000
Cow Cannon - Unlock in Story Mode / Available after the "Get Cows to Higher Ground" / $2500